Please use this identifier to cite or link to this item: http://idr.nitk.ac.in/jspui/handle/123456789/11043
Title: Ethyl 2-[(3-chloro-phen-yl)hydrazono]-3-oxobutanoate
Authors: Fun, H.-K.
Padaki, M.
Sowmya
Isloor, A.M.
Chantrapromma, S.
Issue Date: 2009
Citation: Acta Crystallographica Section E: Structure Reports Online, 2009, Vol.65, 6, pp.o1320-o1321
Abstract: The mol-ecule of the title oxobutanoate derivative, C12H 13ClN2O3, adopts a keto-hydrazo tautomeric form and is roughly planar, the angle between the benzene ring and the mean plane through the hydrazone and aliphatic chain being 1.49 (6) . This planarity is further aided by the formation of an intra-molecular N - H?O hydrogen bond which generates an S(6) ring motif. The aromatic ring and aliphatic chain have a trans configuration with respect to the N - N bond. In the crystal packing, centrosymmetric R 2 2(16) dimers are formed through pairs of weak C - H?O(3-oxo) inter-actions. These dimers are linked together through weak C - H?O(carboxyl-ate C=O) inter-actions into ribbons along the b-axis direction. These ribbons are stacked along the a-axis direction. The crystal also exhibits Cl?Cl [3.4988 (6) ] and C?O [3.167 (2)-3.335 (2) ] short contacts.
URI: http://idr.nitk.ac.in/jspui/handle/123456789/11043
Appears in Collections:1. Journal Articles

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