Please use this identifier to cite or link to this item: http://idr.nitk.ac.in/jspui/handle/123456789/12172
Title: Nano Fe3O4@APTES@Ni(OH)2 as a catalyst for alcohol oxidation
Authors: Bhat, P.B.
Bhat, B.R.
Issue Date: 2015
Citation: New Journal of Chemistry, 2015, Vol.39, 1, pp.273-278
Abstract: A nanorod shaped nickel hydroxide coated ferrite nanocatalyst was synthesized by a traditional co-precipitation method. The particle size of the nanoferrite was tuned using a variable surfactant ratio to achieve a high surface area. A very high BET surface area (334.55 m2 g-1) was achieved for particles with sizes of 40-130 nm. The superparamagnetic reusable catalyst was found to be active for the selective liquid phase oxidation of alcohols with hydrogen peroxide as a mild oxidant. Nickel hydroxide acted as a Bronsted base working in synergy with the nanoferrite catalyst for alcohol oxidation. The catalytic system was found to catalyse primary and secondary alcohols efficiently (86%) to their corresponding carbonyls in good yields. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015.
URI: http://idr.nitk.ac.in/jspui/handle/123456789/12172
Appears in Collections:1. Journal Articles

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