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http://idr.nitk.ac.in/jspui/handle/123456789/12968| Title: | Palladium complex in a room temperature ionic liquid: A convenient recyclable reagent for catalytic oxidation |
| Authors: | Dileep, R. Bhat, B.R. Kumara, T.H.S. |
| Issue Date: | 2014 |
| Citation: | Green Chemistry Letters and Reviews, 2014, Vol.7, 1, pp.32-36 |
| Abstract: | Palladium (Pd)-catalyzed carbonylation of alcohols proceeds in ionic liquid (IL) media (1-ethyl-3-methylimidazolium hexafluorophosphate). Carbonylation of primary/secondary alcohols to aldehydes/ketones was greatly accelerated by the use of a Pd-based catalyst in the presence of NaOCl as an oxidant. The catalyst was more easier to recycle in the IL [Emim]PF6 with an equal-proportioned CH2Cl2 than in the single CH2Cl2 or IL. 2014 The Author(s). Published by Taylor & |
| URI: | http://idr.nitk.ac.in/jspui/handle/123456789/12968 |
| Appears in Collections: | 1. Journal Articles |
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