Please use this identifier to cite or link to this item: http://idr.nitk.ac.in/jspui/handle/123456789/13228
Title: Synthesis and characterization of schiff base metal complexes and reactivity studies with malemide epoxy resin
Authors: Lakshmi, B.
Shivananda, K.N.
Prakash, G.A.
Isloor, A.M.
Mahendra, K.N.
Issue Date: 2012
Citation: Bulletin of the Korean Chemical Society, 2012, Vol.33, 2, pp.473-482
Abstract: A novel malemide epoxy containing Co(II), Ni(II) and Cu(II) ions have been synthesized by curing malemide epoxy resin (MIEB-13) and Co(II), Ni(II) and Cu(II) complexes of macrocyclic bis-hydrazone Schiff base. The Schiff base was synthesized by reacting 1,4-dicarbnyl phenyl dihydrazide with 2,6-diformyl-4-methyl phenol. The Schiff base and its Co(II), Ni(II) and Cu(II) complexes have been characterized by elemental analyses, spectral (IR, 1H NMR, UV-vis., FAB mass, ESR), thermal and magnetic data. The curing reaction of maleimide epoxy compound with metal complexes was studied as curing agents. The stability of cured samples was studied by thermo-gravimetric analyses and which have excellent chemical (acid/alkali/solvent) and water absorption resistance. Further, the scanning electron microscopy (SEM) and definitional scanning colorimetric (DSC) techniques were confirmed the phase homogeneity of the cured systems.
URI: http://idr.nitk.ac.in/jspui/handle/123456789/13228
Appears in Collections:1. Journal Articles

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